Aqua­bis(1H-imidazole-κN 3)bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II)

نویسندگان

  • Wen-Dong Song
  • Run-Zhen Fan
  • Hong-Mian Wu
چکیده

In the mononuclear title compound, [Ni(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Ni(II) atom is coordinated by three carboxylate O atoms (from a bidentate 4-methyl-benzoate ligand and a monodentate 4-methyl-benzoate ligand), two N atoms (from two imidazole ligands) and a water mol-ecule in an octa-hedral geometry. Inter-molecular O-H⋯O hydrogen-bonding inter-actions lead to infinite chains, which are further self-assembled into a supra-molecular network through inter-molecular N-H⋯O hydrogen-bonding inter-actions and π-π stacking [centroid-centroid distance = 3.717 (2) Å].

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008